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⚡ What Is a Lewis Dot Structure?

A Lewis dot structure (also called an electron dot diagram) is a simple drawing that shows how the valence electrons — the outermost electrons — of an atom are arranged around it, and how atoms share or transfer those electrons to form chemical bonds.

They were invented by chemist Gilbert N. Lewis in 1916 and remain the most widely used tool for predicting molecular shape and reactivity.

🔑 Core Idea
Each dot represents one valence electron. When two atoms share a pair of dots, that's a covalent bond. When one atom gives electrons to another, that's an ionic bond.
🔵 Valence Electrons — The Dots

Valence electrons are in the outermost shell of an atom. They're the only ones that participate in bonding. The number of valence electrons equals the element's group number (for main-group elements).

1️⃣
Group 1 (Alkali Metals)
1 valence electron. Very eager to give it away. Example: Sodium (Na).
4️⃣
Group 14 (Carbon family)
4 valence electrons. Can form 4 bonds in any direction. Carbon is the basis of organic chemistry.
7️⃣
Group 17 (Halogens)
7 valence electrons — just 1 short of a full shell. Very reactive; love to gain one electron.
8️⃣
Group 18 (Noble Gases)
8 valence electrons (except He with 2). Already full — don't bond under normal conditions.
⭕ The Octet Rule

Most atoms are most stable when they have 8 electrons in their outermost shell — a full octet. This drives all chemical bonding: atoms bond to complete their octets, either by sharing electrons (covalent bonds) or transferring them (ionic bonds).

🔗 Covalent Bond
Two nonmetals share a pair of electrons. Both atoms count the shared electrons toward their octet. Example: H₂O, CO₂, CH₄.
⚡ Ionic Bond
A metal transfers electrons to a nonmetal. Both end up with full shells. Example: NaCl (table salt).
🔗 Types of Covalent Bonds

When two atoms share electrons, they can share 1, 2, or 3 pairs. More shared pairs = stronger, shorter bond.

Single Bond ( — )
1 shared pair of electrons (2 electrons). Example: H–H in H₂, C–H in methane.
Double Bond ( = )
2 shared pairs (4 electrons). Shorter and stronger than a single bond. Example: O=O in O₂, C=O in CO₂.
Triple Bond ( ≡ )
3 shared pairs (6 electrons). Very short and very strong. Example: N≡N in N₂, C≡C in acetylene.
Lone Pairs
Pairs of electrons not used for bonding. They still count toward the octet and affect molecular shape.
🔢 Drawing Lewis Dot Structures — Step by Step

We'll use water (H₂O) as our worked example — one of the most important molecules in chemistry. Follow each step in order to see how the Lewis dot structure is built from scratch.

Step 1
🧪 Select a Molecule
🔬 Lewis Dot Structure
Bond Legend
Single bond
Double bond
Triple bond
•• Lone pair
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